Reductive desulfurization using the Raney nickel - Sodium hypophosphite combination system without racemization of a secondary alcohol

DOI: 10.1016/0040-4039(96)00273-0

Source and publish data:

Tetrahedron Letters p. 2271 - 2274 (1996)

Update date:2022-08-11

Topics:

Authors:

Nishide, Kiyoharu

Shigeta, Yukihiro

Obata, Kenichi

Inoue, Takehisa

Node, Manabu

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Article abstract of DOI:10.1016/0040-4039(96)00273-0

Thioethers bearing an optically active secondary alcohol were desulfurized with Raney nickel - sodium hypophosphite - acetate buffer system to give optically active alcohols without racemization in high yields. This Raney nickel combination system exhibited a unique desulfurization of benzylthio or phenylthio group in the presence of benzyl ether.

Full text of DOI:10.1016/0040-4039(96)00273-0

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