Journal of Organic Chemistry p. 5872 - 5876 (2019)
Update date:2022-08-17
Topics:
Zhou, He-Ye
Han, Ying
Shi, Qiang
Chen, Chuan-Feng
Directional transportation of a helic[6]arene along a nonsymmetric molecular axle was achieved, which was easily performed in dichloromethane by a stopper reaction and subsequent addition of fluoride ions. In this system, the fluoride ions could act as a versatile stimulus to unidirectionally release the macrocycle that not only destroyed the host-guest interaction but also removed the silyl stopper.
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