Tetrahedron Letters p. 555 - 556 (1994)
Update date:2022-08-31
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Bott
When generated in dichloromethane, the Reformatzky reagent from ethyl bromoacetate can react with diphenylchloromethane, 1-bromoadamantane and 1-phenylethyl chlorides to form the corresponding α-substituted ethyl acetates in excellent to good yields. The mechanism of these Reformatzky reactions is interpreted in terms of a carbocation as intermediate which originates from the interaction of the alkyl halide with the organozinc bromide.
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