A zerovalent nickel-2,2'-bipyridine complex: an efficient catalyst for electrochemical homocoupling of ortho-substituted halides and their heterocoupling with meta- and para-substituted halides

DOI: 10.1016/0022-328X(87)85158-6

Source and publish data:

Journal of Organometallic Chemistry p. 263 - 268 (1987)

Update date:2022-08-29

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Authors:

Meyer, Gilbert

Rollin, Yolande

Perichon, Jacques

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Article abstract of DOI:10.1016/0022-328X(87)85158-6

Electroreduction of ortho-substituted halides Ar-X in a nickel-2,2'-bipyridyl system and N-methylpyrrolidone as solvent gave the homocoupling product ArAr.The nickel-2,2'-bipyridyl system is also a catalyst for the electrochemical heterocoupling of ArX with meta- or para-substituted halides Ar'X'.

Full text of DOI:10.1016/0022-328X(87)85158-6

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