Chemical and Pharmaceutical Bulletin p. 930 - 932 (1993)
Update date:2022-08-30
Topics:
Kurokawa-Nose
Shimada
Wada
Tanaka
Murakami
Saiki
A novel 2-tetralol-type xyloside, named asplenoside, was isolated from the fronds of Asplenium wilfordii. The structure was determined as (6R)-5,6,7,8-tetrahydro-6-β-D-xylopyranosyloxy-2-naphthalenecarboxyli c acid by chemical and spectral means. Application of the glycosylation shift rule in 13C-NMR spectroscopy to the determination of the absolute configuration is described.
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