Synthetic Communications p. 3517 - 3521 (2000)
Update date:2022-08-11
Topics:
Zheng
Bao
Zhang
Promoted by metallic cadmium allylilic and propargyl bromides react smoothly with aldehydes in aqueous DMF to give homoallylic and homopropargyl alcohols in moderate to good yields. It can also promote pinacol coupling of aromatic aldehydes. The metallic cadmium is produced in situ by the reduction of CdCl2 · H2O with samarium metal.
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