Carbonyl Ylide Formation from the Rhodium(II) Acetate Catalysed Rection of Keto α-Diazoacetate Derivatives

DOI: 10.1039/c39890000921

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 921 - 922 (1989)

Update date:2022-08-23

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Authors:

Dean, Dennis C.

Krumpe, Keith E.

Padwa, Albert

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Article abstract of DOI:10.1039/c39890000921

Formation of carbonyl ylides from the reaction of keto α-diazoacetates with rhodium(II) acetate has been found to be dependent on the electrophilicity of the intermediate rhodium carbenoid.

Full text of DOI:10.1039/c39890000921

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