Journal of the Chemical Society. Chemical communications p. 1210 - 1211 (1984)
Update date:2022-08-17
Topics:
Rimmelin, Paul
Taghavi, Hamid
Sommer, Jean
Methyl ethyl ether is formed by treating trimethyloxonium hexachloroantimonate with the strongly hindered base, 2,2,6,6-tetramethylpiperidyl-lithium; this reaction is attributed to the formation of an oxygen ylide followed by a Stevens-type rearrangement or intermolecular methylation.
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