Journal of the Chemical Society. Chemical communications p. 324 - 325 (1990)
Update date:2022-08-11
Topics:
Mitsuhashi, Tsutomu
Hirota, Hiroshi
The decomposition of t-butyl(nitro)malononitrile in dimethyl sulphoxide at 80 deg C gives isobutene (65percent) as a product arising from a t-butyl cation generated via carbon-carbon bond heterolysis which proceeds eleven times faster than the carbon-chlorine bond heterolysis of t-butyl chloride.
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