Journal of the Chemical Society. Perkin transactions II p. 1452 - 1456 (1980)
Update date:2022-08-30
Topics:
Jackson, Richard A
Townson, Michael
When hexafluoroacetone is photolysed in the presence of neopentane at 300 deg C, isobutane is formed as a primary product, and 1,1,1-trifluoroethane is formed in amounts much greater than would be expected from combination of methyl and trifluoromethyl radicals.These results strongly support the occurence of a homolytic bimolecular substitution reaction (SH2) by a trifluoromethyl radical at a methyl carbon atom, with the displacement of a t-butyl radical.
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