Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2457 - 2461 (1990)
Update date:2022-08-11
Topics:
Slivinskii, E. V.
Markova, N. A.
Teleshev, A. T.
Korneeva, G. A.
Butkova, O. L.
et al.
The factor responsible for the deactivation of a carbonyl triphenylphosphite rhodium hydroformylation catalyst appears to be the formation of a chelate-structure complex with diphenylphosphite, which is the product of partial hydrolysis of the organophosphorus ligand.The deactivating effect of diphenylphosphite can be supressed upon interaction of the H(O)P(OPh)2 and P(OPh)3-modified complex with 2-butenes under hydroformylation reaction conditions.
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