Reactions of sterically hindered organozinc and organocadmium compounds containing functional silicon centres. Crystal structures of Zn2 and Cd2

DOI: 10.1016/0022-328X(92)83430-P

Source and publish data:

Journal of Organometallic Chemistry p. 41 - 55 (1992)

Update date:2022-08-31

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Authors:

Al-Juaid, Salih S.

Eaborn, Colin

Habtemariam, Abraha

Hitchcock, Peter B.

Smith, J. David

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Article abstract of DOI:10.1016/0022-328X(92)83430-P

The compound (Me3Si)2CCl2 was converted by treatment with BuLi/Et2O/THF and then with Me2HSiCl into (Me3Si)2CCl(SiMe2H).Further lithiation with BuLi gave LiC(SiMe3)2(SiMe2H), which reacted with ZnBr2 to yield Zn2.Thence, several new org

Full text of DOI:10.1016/0022-328X(92)83430-P

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