Synthesis of Difluoroenoxysilanes from Acylsilanes and Trifluoromethyltrimethylsilane (TFMTMS). Dramatic Effect of the Catalytic Fluoride Source

DOI: 10.1039/c39940002117

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2117 - 2118 (1994)

Update date:2022-08-11

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Authors:

Brigaud, Thierry

Doussot, Pascale

Portella, Charles

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Article abstract of DOI:10.1039/c39940002117

Difluoroenoxysilanes are produced in high yield by catalytic fluoride activation of a mixture of TFMTMS and an acylsilane: Tetrabutylammonium difluorotriphenylstannate is an excellent catalyst whereas tetrabutylammonium fluoride leads directly to the aldo

Full text of DOI:10.1039/c39940002117

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