Bulletin of the Chemical Society of Japan p. 3455 - 3461 (1992)
Update date:2022-08-16
Topics:
Chowdhury, Pradyot Kumar
Real time observation of retro-Diels-Alder dissociation of decafluorocyclohexene into tetrafluoroethylene and hexafluorobutadiene induced by transversely excited atmospheric pulsed CO2 laser is reported.The formation rate and the red-shifted absorption spectra of nascent hexafluorobutadiene suggest substantial internal energy incorporation, which appears to be sufficient for its undergoing electrolytic transformation to hexafluorocyclobutene at a rate corresponding to the decay kinetics.When the above IR multiphoton dissociation of decafluorocyclohexene occurs in presence of oxygen, UV light emission due to COF2* is observed.
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