STUDIES IN POLYETHER SYNTHESIS USING POLYEPOXYDE CYCLISATIONS.

DOI: 10.1016/S0040-4039(00)95630-2

Source and publish data:

Tetrahedron Letters p. 5205 - 5208 (1987)

Update date:2022-08-16

Topics:

Authors:

Paterson, Ian

Boddy, Ian

Mason, Ian

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Article abstract of DOI:10.1016/S0040-4039(00)95630-2

The acid-catalysed directed cyclisation of mono-, di-, and triepoxy t-butyl ester derivatives is used for the asymmetric synthesis of various polyether-type fragments including a C13-C27 fragment of etheromycin.The epoxide stereochemistry is set up by Sharpless epoxidation of allylic and homoallylic alcohols.

Full text of DOI:10.1016/S0040-4039(00)95630-2

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