Tetrahedron Letters p. 5205 - 5208 (1987)
Update date:2022-08-16
Topics:
Paterson, Ian
Boddy, Ian
Mason, Ian
The acid-catalysed directed cyclisation of mono-, di-, and triepoxy t-butyl ester derivatives is used for the asymmetric synthesis of various polyether-type fragments including a C13-C27 fragment of etheromycin.The epoxide stereochemistry is set up by Sharpless epoxidation of allylic and homoallylic alcohols.
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