STEREOSELECTIVE PIG LIVER ESTERASE-CATALYZED HYDROLYSIS OF RIGID BICYCLIC MESO-DIESTERS : PREPARATION OF OPTICALLY PURE 4,7-EPOXYTETRA- AND HEXA-HYDROPHTHALIDES.

DOI: 10.1016/S0040-4039(00)89299-0

Source and publish data:

Tetrahedron Letters p. 4087 - 4090 (1985)

Update date:2022-08-11

Topics:

Authors:

Bloch, R.

Guibe-Jampel, E.

Girard, C.

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Article abstract of DOI:10.1016/S0040-4039(00)89299-0

The bicyclic and rather rigid meso-diesters 1 - 3 have been found to be good substrates for pig liver esterase.The half-esters obtained have been converted to either one of the enantiomers of tricyclic lactones, of potential value for natural product synthesis.

Full text of DOI:10.1016/S0040-4039(00)89299-0

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