Stereoselective 1,2-cis-galactosylation assisted by remote neighboring group participation and solvent effects

DOI: 10.1016/S0040-4039(99)01203-4

Source and publish data:

Tetrahedron Letters p. 6523 - 6526 (1999)

Update date:2022-08-23

Topics:

Authors:

Demchenko, Alexei V.

Rousson, Emmanuel

Boons, Geert-Jan

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Article abstract of DOI:10.1016/S0040-4039(99)01203-4

Iodonium-ion promoted glycosylations in 1,4-dioxane/toluene with galactosyl donors having an electrondonating neighboring group participating functionality at C-4 give exceptional high α-anomeric selectivities.

Full text of DOI:10.1016/S0040-4039(99)01203-4

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Product name:6-O-(2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl)-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranoside

Cas No:117841-66-4

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