Synthesis of α-Hydroxy Carbonyl Compounds (Acyloins): Direct Oxidation of Enolates Using 2-Sulfonyloxaziridines

DOI: 10.1021/jo00191a048

Source and publish data:

Journal of Organic Chemistry p. 3241 - 3243 (1984)

Update date:2022-08-28

Topics:

Authors:

Davis, Franklin A.

Vishwakarma, Lal C.

Billmers, Joanne M.

Finn, John

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Article abstract of DOI:10.1021/jo00191a048

Direct oxidation of ketone and ester enolates, using 2-sulfonyloxaziridine 1, affords α-hydroxy carbonyl compounds (acyloins) in high yield with excellent stereoselectivity.

Full text of DOI:10.1021/jo00191a048

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