ELECTROGENERATED BASES VII. NOVEL SYNTHESES OF ETHYL GLYOXALATE AND DIETHYL KETOMALONATE VIA ELECTROGENERATED SUPEROXIDE

DOI: 10.1016/S0040-4039(00)81889-4

Source and publish data:

Tetrahedron Letters p. 2223 - 2226 (1983)

Update date:2022-08-17

Topics:

Authors:

Sugawara, M.

Baizer, M. M.

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Article abstract of DOI:10.1016/S0040-4039(00)81889-4

Using electrogenerated tetraalkylammonium superoxide plus oxygen ethyl cyanoacetate has been converted (a) directly to ethyl glyoxylate and (b) in a "one-pot" two-step synthesis to the oxomalonate.

Full text of DOI:10.1016/S0040-4039(00)81889-4

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