Quenching of Triplet Benzophenone by 1,4-Diazabicyclooctane in Acetonitrile Revisited

Article abstract of DOI:10.1021/j100172a001

In conditions of laser flash photolysis, the kinetics of decay of the absorption of the benzophenone radical anion show that free, solvated ions are formed after electron transfer between the title compounds in neat, dry acetonitrile.Furthermore, it is shown that the opposite conclusion claimed by Devadoss and fessenden (J.Phys.Chem., 1990, 94, 4540), i.e., no ion pair dissociation, results from a misinterpretation of the transient decay rate.