Chemistry Letters p. 601 - 602 (1982)
Update date:2022-08-17
Topics:
Fukagawa, Toshihiro
Fujiwara, Yuzo
Taniguchi, Hiroshi
Phenylytterbium iodide (Ph-Yb-I) has been found to react with benzoyl chloride to give both triphenylcarbinol and benzophenone.When Ph-Yb-I is added inversely to benzoyl chloride, especially in the presence of FeCl3, the ketone is obtained selectively in modest yields in contrast to the Grignard reaction.
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