Chemistry Letters p. 601 - 604 (1986)
Update date:2022-08-11
Topics:
Maruyama, Kazuhiro
Hayami, Jun-ichi
Katagiri, Toshimasa
Intermediates in the reaction of Grignard reagent with benzophenone in THF were investigated by both ESR and stopped-flow techniques.The short-lived (blue colored) and other long-lived (pink colored radical) intermediates were observed.The pink colored radical intermediate could be in a state of dimeric aggregate of benzophenone anion radicals ion-paired with Grignard cation <"RMgBr">+ in solution.
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