Reactions in Dry Media: Oxidative Cleavage of Olefins Adsorbed on Inorganic Supports with Oxygen

DOI: 10.1021/jo00201a038

Source and publish data:

Journal of Organic Chemistry p. 149 - 150 (1985)

Update date:2022-08-11

Topics:

Authors:

Aronovitch, Chaim

Mazur, Yehuda

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Article abstract of DOI:10.1021/jo00201a038

Substituted phenylethylenes adsorbed on inorganic supports are oxidatively cleaved to ketones or aldehydes under illumination in the presence of oxygen.It is suggested that these oxidations invove the intermediacy of cation radicals whose formation is initiated by contact charge-transfer interactions between the olefins on the adsorbing phase and oxygen molecules.

Full text of DOI:10.1021/jo00201a038

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