Reactions in Dry Media: Oxidative Cleavage of Olefins Adsorbed on Inorganic Supports with Oxygen

DOI: 10.1021/jo00201a038

Source and publish data:

Journal of Organic Chemistry p. 149 - 150 (1985)

Update date:2022-08-11

Topics:

Authors:

Aronovitch, Chaim

Mazur, Yehuda

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00201a038

Substituted phenylethylenes adsorbed on inorganic supports are oxidatively cleaved to ketones or aldehydes under illumination in the presence of oxygen.It is suggested that these oxidations invove the intermediacy of cation radicals whose formation is initiated by contact charge-transfer interactions between the olefins on the adsorbing phase and oxygen molecules.

Full text of DOI:10.1021/jo00201a038

Products guided by the article

Product name:Benzophenone

Cas No:119-61-9

R&D Labs maybe for 119-61-9

Jiaozuo Zhongwen Trading Coporation Limited

Contact:--

Address:East Renmin Road
N&R INDUSTRIES,INC

Contact:Tel:+86-29-88764861 Fax:+86-29-88764861

Address:Rm#2107, Block A, Epin Meidao Building, Gaoxin Rd, Hi-Tech Zone, Xi’an, China
Zhejiang kehong chemical co., ltd

Contact:0086-575-85522000

Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Shanghai Surseechem Co.,Ltd.

Contact:+86-21-61318535

Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai

Relevant to this article

Discovery of 2-(1-(3-(4-Chloroxyphenyl)-3-oxo-propyl)pyrrolidine-3-yl)-1H-benzo[d]imidazole-4-carboxamide: A Potent Poly(ADP-ribose) Polymerase (PARP) Inhibitor for Treatment of Cancer

Doi:10.3390/molecules24101901
(2019)
Identification and Development of 2,3-Dihydropyrrolo[1,2-a]quinazolin-5(1H)-one Inhibitors Targeting Bromodomains within the Switch/Sucrose Nonfermenting Complex

Doi:10.1021/acs.jmedchem.5b01997
(2016)
The α-Glycosidation of Partially Unprotected N-Acetyl and N-Glycolyl Sialyl Donors in the Absence of a Nitrile Solvent Effect

Doi:10.1002/chem.201601031
(2016)
A Series of Metal-Organic Frameworks for Selective CO₂ Capture and Catalytic Oxidative Carboxylation of Olefins

Doi:10.1021/acs.inorgchem.8b02293
(2018)
Facile synthesis of fructone from ethyl acetoacetate and ethylene glycol catalyzed by SO₃H-functionalized Bronsted acidic ionic liquids

Doi:10.1039/c4ra01708k
(2014)
Chemically modified "polar patch" mutants of subtilisin in peptide synthesis with remarkably broad substrate acceptance: Designing combinatorial biocatalysts

Doi:10.1002/1521-3765(20020916)8:18<4129::AID-CHEM4129>3.0.CO;2-V
(2002)

Article Doi