INTRAMOLECULAR ACYLATION OF VINYLIC SILANES. A NOVEL, GENERAL APPROACH FOR THE SYNTHESIS OF FOUR- TO SIX-MEMBERED CARBOCYCLIC SYSTEMS AND ITS REGIOCHEMICAL FEATURES

DOI: 10.1016/S0040-4039(00)81530-0

Source and publish data:

Tetrahedron Letters p. 795 - 798 (1983)

Update date:2022-08-31

Topics:

Authors:

Mikami, Koeichi

Kishi, Naoyuki

Nakai, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(00)81530-0

Intramolecular acylations of m-trimethylsilyl-m-alkenoyl chlorides (m = 4 and 5) are described which afford the expected α-alkylidenecycloalkanone and/or the unexpected cycloalkenone, depending upon the substrate struture.

Full text of DOI:10.1016/S0040-4039(00)81530-0

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