Photoinduced electron-transfer reaction of 7,8- disilabicyclo[2.2.2]octa-2,5-dienes

DOI: 10.1016/S0040-4039(98)02546-5

Source and publish data:

Tetrahedron Letters p. 1133 - 1136 (1999)

Update date:2022-08-10

Topics:

Authors:

Kako Kako

Hatakenaka

Kakuma Kakuma

Ninomiya

Nakadaira

Yasui Yasui

Iwasaki Iwasaki

Wakasa Wakasa

Hayashi Hayashi

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Article abstract of DOI:10.1016/S0040-4039(98)02546-5

9,10-Dicyanoanthracene-sensitized irradiation of 7,8- disilabicyclo[2.2.2]octa-2-5-dienes1-3 in the presence of MeOH resulted in the formation of dimethoxydisilanes and the corresponding aromatic compounds. A stepwise mechanism involving C-Si bond cleavage by MeOH is proposed.

Full text of DOI:10.1016/S0040-4039(98)02546-5

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