The microwave spectrum of the SiN(2Σ+) radical

Article abstract of DOI:10.1063/1.444682

The microwave absorption spectrum of the SiN radical has been detected in a dc glow discharge in a SiCl4 or SiH4/N2 mixture.The three rotational transitions N = 2<--1, 3<--2, and 4<--3, have been observed in the frequency region 87 to 175 GHz by using a source-frequency modulation microwave spectrometer.The rotational constant, the centrifugal distortion constant, the spin-rotation coupling constant, and the magnetic hyperfine coupling constants b and c and the electric quadrupole coupling constant of the nitrogen nucleus have been precisely determined.The electronic structure of the SiN molecule has been briefly discussed using the magnetic hyperfine coupling constants and also the quadrupole coupling constant <3.05(23) MHz> of 14N.

Full text of DOI:10.1063/1.444682

The microwave spectrum of the SiN(2Σ+) radical
Shuji Saito, Yasuki Endo, and Eizi Hirota
Citation: The Journal of Chemical Physics 78, 6447 (1983); doi: 10.1063/1.444682
View online: http://dx.doi.org/10.1063/1.444682
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/78/11?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
28.42.202.150 On: Mon, 24 Nov 2014 07:03:40
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
28.42.202.150 On: Mon, 24 Nov 2014 07:03:40
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
28.42.202.150 On: Mon, 24 Nov 2014 07:03:40
1

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
28.42.202.150 On: Mon, 24 Nov 2014 07:03:40
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