The chemistry of monoanionic carbaborane ligands. Synthesis, and molecular and electronic structure of , and order-of-magnitude improved structure of <η-C5H5)Mn(CO)3

Article abstract of DOI:10.1016/0022-328X(90)87218-3

The synthesis, and spectroscopic and structural characterisation of a transition metal complex of, formally, a monoanionic carbaborane ligand are described.Two molecules of <3,3,3-(CO)3-4-SMe2-3,2,1-MnC2B9H10> crystallise in the triclinic space group P1,