Journal of the Chemical Society. Chemical communications p. 255 - 257 (1990)
Update date:2022-08-11
Topics:
Wan, Peter
Budac, David
Krogh, Erik
A new photoreaction, the photoketonization of dibenzosuberenol (1) to dibenzosuberone (2) in aqueous solution, is reported, the mechanism of which is believed to involve initial ionization of the C-H proton at the 5-position (in S1), to generate a 5-hydroxy-5-dibenzosuberenyl (9) carbanion intermediate.
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Doi:10.1021/ja01155a021
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