SURFACE ENHANCED ENANTIODIFFERENTIATION IN REACTIONS OF CHIRAL ACETOACETATES

DOI: 10.1016/S0040-4039(00)80562-6

Source and publish data:

Tetrahedron Letters p. 4615 - 4618 (1988)

Update date:2022-08-16

Topics:

Authors:

Bram, Georges

Cabaret, Daniel

Welvart, Zoltan

Geraghty, Niall W. A.

Garwey, James

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Article abstract of DOI:10.1016/S0040-4039(00)80562-6

The stereoselectivity of the alkylation of chiral acetoacetates by racemic secondary alkyl halides changes when the reaction is carried out on a solid support; the change can be interpreted in terms of a model involving surface imposed conformational restrictions.

Full text of DOI:10.1016/S0040-4039(00)80562-6

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