New chiral phosphinooxazolidine ligands for palladium-catalyzed asymmetric allylic substitution

DOI: 10.1016/S0040-4039(99)00936-3

Source and publish data:

Tetrahedron Letters p. 5197 - 5198 (1999)

Update date:2022-08-30

Topics:

Authors:

Jin, Myung-Jong

Jung, Jung-Ae

Kim, Sang-Han

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Article abstract of DOI:10.1016/S0040-4039(99)00936-3

New chiral phosphinooxazolidines were prepared and examined as chiral ligands in Pd-catalyzed asymmetric allylic substitution reaction of 1,3- diphenyl-2- propenyl acetate with dimethyl malonate or benzylamine. Enantioselectivity up to 98% was observed.

Full text of DOI:10.1016/S0040-4039(99)00936-3

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