Journal of the Chemical Society - Faraday Transactions p. 1193 - 1198 (1993)
Update date:2022-08-11
Topics:
Elliot, A. John
Chenier, Monique P.
Ouellette, Denis C.
The g values for the primary species formed in the γ-radiolysis of light and heavy water have been measured as a function of temperature up to 300 deg C.With the exception of g(H2) and g(D2), all the g values are consistent with the generally accepted diffusion-kinetic model of spurs, i.e., with an increase in temperature, the g values of the free radicals increased while those of peroxide decreased.The g values for H2 and D2 increased with temperature which suggests that they are formed by other mechanisms in addition to radical-radical reactions in the spur.
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