Tetrahedron Letters p. 5805 - 5808 (1994)
Update date:2022-08-23
Topics:
Bardin
Barton
Hu
Rojas-Wahl
Taylor
The species responsible for hydrocarbon activation and formation of alkyl chlorides in the Fe(II) and Fe(III)-H2O2 and tert-butyl hydroperoxide systems are identified. The importance of the Fe(II)-Fe(IV) manifold in providing a mechanism which permits the selective functionalization of saturated hydrocarbons by ionic trapping with chloride, azide, and other anions is made manifest. Comparison is made with the Fe(III)-Fe(V) manifold where ionic trapping is never seen.
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Doi:10.1055/s-1987-28071
(1987)Doi:10.1021/jo051372z
(2005)Doi:10.1021/jo01063a025
(1961)Doi:10.1081/SCC-120027269
(2004)Doi:10.1007/BF00696914
()Doi:10.1055/s-2003-42438
(2003)
