Synthetic Studies Targeted at the Cytotoxic 8,9-Seco-ent-kaurene Diterpenes. Concise Complementary Stereocontrolled Construction of the Bridgehead Olefin Core

DOI: 10.1021/jo00279a010

Source and publish data:

Journal of Organic Chemistry p. 4278 - 4279 (1989)

Update date:2022-08-11

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Authors:

Paquette, Leo A.

Ladouceur, Gaetan

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Article abstract of DOI:10.1021/jo00279a010

Methodology for rapid construction of the A/B aubunit of the 8,9-seco-ent-kaurenes is described that takes advantage of complementary stereocontrol in consecutive intramolecular Claisen rearrangement, allylsilane-carboxaldehyde cyclization, and oxy-Cope s

Full text of DOI:10.1021/jo00279a010

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