Chemoenzymatic synthesis of both enantiomers of cispentacin

DOI: 10.1016/S0957-4166(96)00465-X

Source and publish data:

Tetrahedron Asymmetry p. 3565 - 3572 (1996)

Update date:2022-08-17

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Authors:

Theil, Fritz

Ballschuh, Sibylle

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Article abstract of DOI:10.1016/S0957-4166(96)00465-X

Based on the lipase-catalysed kinetic resolution of the silyloxyalcohol (1RS,2SR)-5 by transesterification with vinyl acetate in the presence of lipase from Pseudomonas cepacia a synthesis of both enantiomers of the β-amino acid cispentacin (1R,2S)-1 and (1S,2R)-1 using simple functional group interconversions is described.

Full text of DOI:10.1016/S0957-4166(96)00465-X

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