Journal of Organic Chemistry p. 4267 - 4268 (1989)
Update date:2022-08-10
Topics:
Ragan, John A.
Nakatsuka, Masashi
Smith, David B.
Uehling, David E.
Schreiber, Stuart L.
The addition of a vinyl anion that corresponds to C27 of the immunosuppressant FK-506 to an aldehyde that corresponds to C26 results in a coupling process that is stereoselective and convergent and allows for the direct attachment of the C26-pipecolinate
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