A Highly Enantioselective Asymmetric Hydrogenation Route to β-(2R,3S)-Methyltryptophan

DOI: 10.1016/S0040-4039(98)00604-2

Source and publish data:

Tetrahedron Letters p. 3455 - 3458 (1998)

Update date:2022-08-16

Topics:

Authors:

Hoerrner, R. Scott

Askin, David

Volante, R. P.

Reider, Paul J.

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Article abstract of DOI:10.1016/S0040-4039(98)00604-2

Asymmetric hydrogenation of a protected (Z)-dehydro-β-methyltryptophan derivative 2 with (R,R)-Me-DuPHOS-Rh catalysis was achieved in 97percent ee.Deprotection then afforded (2R,3S)-β-methyltryptophan 1.

Full text of DOI:10.1016/S0040-4039(98)00604-2

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