Tin-free radical chemistry: Intramolecular addition of alkyl radicals to aldehydes and ketones

DOI: 10.1016/S0040-4039(99)01072-2

Source and publish data:

Tetrahedron Letters p. 5511 - 5514 (1999)

Update date:2022-08-17

Topics:

Authors:

Devin, Priscille

Fensterbank, Louis

Malacria, Max

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Article abstract of DOI:10.1016/S0040-4039(99)01072-2

The radical cyclization of several ω-iodoaldehydes and a ketone can be accomplished without the use of tributyltin hydride. Triethylborane in presence of oxygen or light from a sun lamp can serve as a radical initiator and terminator. In these conditions,

Full text of DOI:10.1016/S0040-4039(99)01072-2

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