Tetrahedron p. 2693 - 2702 (1989)
Update date:2022-08-11
Topics:
Marcelis, Antonius T. M.
Plas, Henk C. van der
The reaction of cyclic and non-cyclic enamines with 5-nitropyrimidine has been studied.Many enamines react in an inverse electron-demand Diels-Alder reaction, leading to the formation of 3-nitropyridines.N,S-ketene acetals were also found to react with 5-nitropyrimidines.The mechanism of the reaction will be discussed.
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Doi:10.1021/ja00351a021
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