IR multiple photon dissociation of fluorinated ethanes and ethylenes: HF vibrational energy distributions

Article abstract of DOI:10.1063/1.439280

The IR multiple photon dissociation of fluorinated ethanes and ethylenes produces vibrationally excited HF via collisionless molecular elimination.The HF(excit.) fluorescence spectra have been measured and analyzed in order to determine the relative vibrational level populations produced by the dissociation processes.These results are compared to those obtained by others who used alternate methods of excitation.The measured vibrational level distributions cannot be adequately represented by single temperature Boltzmann distributions or by a statistical partitioning of the available energy.It is estimated that less than 30percent of the fixed energy appears as vibrational excitation of the HF fragment.

Full text of DOI:10.1063/1.439280

IR multiple photon dissociation of fluorinated ethanes and ethylenes: HF vibrational
energy distributions
C. R. Quick Jr. and C. Wittig
Citation: The Journal of Chemical Physics 72, 1694 (1980); doi: 10.1063/1.439280
View online: http://dx.doi.org/10.1063/1.439280
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/72/3?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
31.193.242.161 On: Tue, 09 Dec 2014 16:28:01
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
31.193.242.161 On: Tue, 09 Dec 2014 16:28:01
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
31.193.242.161 On: Tue, 09 Dec 2014 16:28:01
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
31.193.242.161 On: Tue, 09 Dec 2014 16:28:01
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
31.193.242.161 On: Tue, 09 Dec 2014 16:28:01
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