Vibrational energy disposal in polyatomic ion-molecule reactions: SF6- + H, D SF5- + HF(υ), DF(υ)

Article abstract of DOI:10.1063/1.446942

Vibrational state distributions of the , DF(ν = 0-12) ion- molecule reactions are investigated with the flowing afterglow-infrared chemiluminescence technique.The nascent distribution for the hydrogen reaction is

, and for the deuterium

Full text of DOI:10.1063/1.446942

Vibrational energy disposal in polyatomic ion–molecule reactions: SF− 6+H, D→SF−  

+HF(v), DF(v)  

5

Charles E. Hamilton, Veronica M. Bierbaum, and Stephen R. Leone  

Citation: The Journal of Chemical Physics 80, 1831 (1984); doi: 10.1063/1.446942  

View online: http://dx.doi.org/10.1063/1.446942  

View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/80/5?ver=pdfcov  

Published by the AIP Publishing  

Articles you may be interested in  

Flowing afterglow infrared chemiluminescence studies of vibrational energy disposal in the ion–molecule  

reactions F−+HBr,DBr→HF,DF+Br−  

J. Chem. Phys. 83, 3913 (1985); 10.1063/1.449102  

Nascent product vibrational state distributions of ion–molecule reactions: The H+F−→HF(v)+e − associative  

detachment reaction  

J. Chem. Phys. 75, 4885 (1981); 10.1063/1.441926  

Ion–molecule reactions of SF6: Determination of I.P.(SF5), A.P.(SF5 +/SF6), and D(SF5–F)  

J. Chem. Phys. 74, 5700 (1981); 10.1063/1.440934  

Rate constants and vibrational energy disposal for reaction of H atoms with Br2, SF5Br, PBr3, SF5, and SF4  

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Effect of changing reagent energy. X. Vibrational threshold energies for alternative reaction paths  

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Full text of DOI:10.1063/1.446942

Vibrational energy disposal in polyatomic ion–molecule reactions: SF− 6+H, D→SF−
+HF(v), DF(v)
5
Charles E. Hamilton, Veronica M. Bierbaum, and Stephen R. Leone
Citation: The Journal of Chemical Physics 80, 1831 (1984); doi: 10.1063/1.446942
View online: http://dx.doi.org/10.1063/1.446942
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/80/5?ver=pdfcov
Published by the AIP Publishing
Articles you may be interested in
Flowing afterglow infrared chemiluminescence studies of vibrational energy disposal in the ion–molecule
reactions F−+HBr,DBr→HF,DF+Br−
J. Chem. Phys. 83, 3913 (1985); 10.1063/1.449102
Nascent product vibrational state distributions of ion–molecule reactions: The H+F−→HF(v)+e − associative
detachment reaction
J. Chem. Phys. 75, 4885 (1981); 10.1063/1.441926
Ion–molecule reactions of SF6: Determination of I.P.(SF5), A.P.(SF5 +/SF6), and D(SF5–F)
J. Chem. Phys. 74, 5700 (1981); 10.1063/1.440934
Rate constants and vibrational energy disposal for reaction of H atoms with Br2, SF5Br, PBr3, SF5, and SF4
J. Chem. Phys. 73, 5666 (1980); 10.1063/1.440043
Effect of changing reagent energy. X. Vibrational threshold energies for alternative reaction paths
HF(v)+D→F+HD and →H+DF
J. Chem. Phys. 69, 933 (1978); 10.1063/1.436610
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
128.252.67.66 On: Wed, 24 Dec 2014 02:48:44

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28.252.67.66 On: Wed, 24 Dec 2014 02:48:44
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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