Tetrahedron Letters p. 2299 - 2302 (1999)
Update date:2022-08-10
Topics:
Lehnig, Manfred
15N CIDNP effects observed during nitration of phenolic compounds with nitric and nitrous acid are comparable showing that nitrous acid is not only a catalyst during nitration with nitric acid but also a reactive intermediate. The 15N CIDNP effects are generated in radical pairs formed during encounters of NO2 and arene radical cations or aroxyl radicals. The mechanism given is valid for arenes more reactive than toluene.
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