Chemistry Letters p. 1579 - 1582 (1991)
Update date:2022-08-11
Topics:
Takahashi, Tamotsu
Suzuki, Noriyuki
Kageyama, Motohiro
Nitto, Yu
Saburi, Masahiko
Negishi, Ei-ichi
Hydrogenation reactions of alkenes were catalyzed by zirconium-alkene complex derivatives which were prepared from Cp2ZrCl2 (Cp = η5-C5H5) and n equiv. of RR'CHCH2M (M = MgX or Li).By the use of three or more equiv. of EtMgBr relative to Cp2ZrCl2, the product yield of hydrogenation of 1-decene was remarkably improved most likely due to the stabilization of the Zr(II) species.
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