Journal of Organic Chemistry p. 3776 - 3779 (1988)
Update date:2022-08-17
Topics:
Brower, K.R.
The decomposition of supercritical nitromethane at liquid-like densities gives HCN and CO2 as the principal carbon-containing product whereas at low pressure CH4 and CO predominate.The decomposition is powerfully accelerated by increased density, and a contact ion-pair transition state is inferred.The activation volume is -85 mL/mol.A new method of measurement is described.Various lines of evidence indicate a shift from homolysis at low pressure to rearrangement in dielectric media.
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