Journal of Organic Chemistry p. 3776 - 3779 (1988)
Update date:2022-08-17
Topics:
Brower, K.R.
The decomposition of supercritical nitromethane at liquid-like densities gives HCN and CO2 as the principal carbon-containing product whereas at low pressure CH4 and CO predominate.The decomposition is powerfully accelerated by increased density, and a contact ion-pair transition state is inferred.The activation volume is -85 mL/mol.A new method of measurement is described.Various lines of evidence indicate a shift from homolysis at low pressure to rearrangement in dielectric media.
View More
Contact:+91 9963263336
Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
Wuxi Highness Chemical Co.,Ltd
website:https://www.phtpharmatech.com/
Contact:86-510-81771080
Address:No58 East Xinguan Rd, Guanlin Town, Yixing City, Jiangsu China
Contact:(1) 206-3550089
Address:5115 NE 8TH PL, Renton, WA 98059 USA
website:https://www.bocsci.com/
Contact:1-631-485-4226
Address:Ramsey Road
NanJing KaiHeng Chemical CO., LTD.
Contact:+86-25-85768391
Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
Doi:10.1021/acscatal.5b00952
(2015)Doi:10.1016/j.jcat.2015.09.003
(2015)Doi:10.1016/S0031-9422(00)85030-X
(1984)Doi:10.1002/chem.201604803
(2017)Doi:10.1016/j.tetlet.2011.10.068
(2011)Doi:10.1039/c3cc43203c
(2013)
