Journal of the American Chemical Society p. 6233 - 6236 (1983)
Update date:2022-08-11
Topics:
Rosenfeld
Weiner
Irradiation of acrylic and methacrylic acids at 193 or 249 nm results in decarboxylation. Energy disposal to the CO//2 product is monitored by photofragment infrared fluorescence and is consistent with a dissociation mechanism whereby CO**2 is formed in concert with a carbene. Our results provide some insight regarding the photophysical processes which obtain prior to chemical reaction.
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