CARBON DIOXIDE FIXATION BY LANTHANIDE COMPLEXEX

DOI: 10.1016/S0022-328X(00)99264-7

Source and publish data:

Journal of Organometallic Chemistry p. C29 - C33 (1983)

Update date:2022-08-11

Topics:

Authors:

Bochkarev, M. N.

Fedorova, E. A.

Radkov, Yu. F.

Khorshev, S. Ya.

Kalinina, G. S.

Razyvaev, G. A.

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Article abstract of DOI:10.1016/S0022-328X(00)99264-7

The lanthanide compounds <(Me3Si)2N>mLn3Pr*2CO2*DME at 130-140 deg C in the absence of a solvent.The other complexes did not evolve CO2 on heating.The hydrolysis of the complexes in the open system leads to the evolution of both CO2 molecules.Upon hydrolysis in the closed system carbon dioxide remains in the product containing praseodymium (Me3SiCH2)3SnPr(OH)2*2CO2.

Full text of DOI:10.1016/S0022-328X(00)99264-7

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