The First Structurally Authenticated Divalent Lanthanide Stannyl Derivative

DOI: 10.1039/c39910000779

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 779 - 781 (1991)

Update date:2022-08-17

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Authors:

Cloke, F. Geoffrey N.

Dalby, Christopher I.

Hitchcock, Peter B.

Karamallakis, Helen

Lawless, Gerard A.

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Article abstract of DOI:10.1039/c39910000779

The reaction between YbI2 and Kt)3> affords the diamagnetic ytterbium bis-stannyl derivative 1 (Nep = 2,2-dimethylpropyl and thf = tetrahydrofuran) which has been characterised by multinuclear NMR spectroscopy (119Sn and 171Yb) and X-ray crystallography: reaction of 1 with two equivalents of ArOH (ArOH = 2,6-di-tert-butyl-4-methylphenol) or C5Me5H results in the elimination of Sn(CH2Bu^t)3H to afford the known complexes and respectively whereas the reaction with one equivalent of ArOH or C5Me5 resultsin the formation of the novel mixed ligand complexes t)3>(thf)2> and t)3>(thf)2>.

Full text of DOI:10.1039/c39910000779

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