12. Complete ?-Facial Stereoselectivity in the TiCl4-Mediated Cycloaddition of Cyclopentadiene to N,N-Fumaroyldi

DOI: 10.1002/hlca.19950780114

Source and publish data:

Helvetica Chimica Acta p. 145 - 150 (1995)

Update date:2022-08-18

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Authors:

Chapuis, Christian

Rzepecki, Piotr

Bauer, Tomasz

Jurczak, Janusz

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Article abstract of DOI:10.1002/hlca.19950780114

Under the co-operative influence of two prosthetic groups, and independent of the TiCl4 concentration, complete and constant diastereofacial ?-selection was achieved during the <4 + 2> cycloaddition of cyclopentadiene to N,N'-fumaroyl-di<(2R)-bornane-10,2-sultam>((-)-1c); reactive conformations are discussed.

Full text of DOI:10.1002/hlca.19950780114

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