Heterocyclic Communications p. 575 - 578 (2003)
Update date:2022-08-11
Topics:
Navarro-Eisenstein, Angela M.
Vasquez, Pedro C.
Franklin, Paul J.
Baumstark
The epoxidation of 1,4-dienyl 3-keto steroidal compounds by dimethyldioxirane yields mono-epoxides as the primary products as reported in the literature. Kinetic data show the 1,4-dienyl 3-keto system to be at least ten fold more reactive than simple α,β-
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