
Tetrahedron p. 3587 - 3606 (1995)
Update date:2022-08-16
Topics:
Brown, David S.
Marples, Brian A.
Smith, Paul
Walton, Lesley
Homochiral 2-fluoro-2-substituted-1-tetralones (10a, 10b, 13) and ethyl 2-fluoro-1-indanone-2-carboxylate (16) have been isolated.The dioxirane derivatives of these ketones have been prepared in situ, and have been shown to epoxidise alkenes but not enantioselectively.The dioxirane derivative of methyl 2,5,7-trifluoro-1-indanone-2-carboxylate (18) has been shown to be comparatively efficient in epoxidation.
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Doi:10.1007/BF00960364
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(2018)Doi:10.1006/jcat.1995.1341
(1995)Doi:10.1016/j.tet.2015.10.008
(2015)Doi:10.1021/ol048159u
(2004)Doi:10.1007/BF00809187
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