Substituent Effects on the Stereoselectivity of the Acid-Catalyzed Solvolysis of Rigid 1-Arylcyclohexene Oxides. Further Evidence for a Mechanism Implying Different Benzylic Carbocationic Species

DOI: 10.1021/ja00239a028

Source and publish data:

Journal of the American Chemical Society p. 1463 - 1469 (1987)

Update date:2022-08-28

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Authors:

Crotti, Paolo

Dell'Omodarme, Giuliana

Ferretti, Maria

Macchia, Franco

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Article abstract of DOI:10.1021/ja00239a028

The substituent effect on the stereoselctivity of the acid-catalyzed solvolysis of the conformationally rigid diastereoisomeric 4-tert-butyl-1-arylcyclohexene oxides 2 and 3 has been studied.As in the case of the conformationally mobile oxides 1, the syn/

Full text of DOI:10.1021/ja00239a028

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